Highly Efficient Orange and Green Solid‐State Light‐Emitting Electrochemical Cells Based on Cationic IrIII Complexes with Enhanced Steric Hindrance

Highly efficient orange and green emission from single‐layered solid‐state light‐emitting electrochemical cells based on cationic transition‐metal complexes [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ (where ppy is 2‐phenylpyridine, dFppy is 2‐(2,4‐difluorophenyl)pyridine, and sb is 4,5‐diaza‐9,9′‐spirobifluorene) is reported. Photoluminescence measurements show highly retained quantum yields for [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂ sb]PF₆ in neat films (compared with quantum yields of these complexes dispersed in m‐bis(N‐carbazolyl)benzene films). The spiroconfigured sb ligands effectively enhance the steric hindrance of the complexes and reduce the self‐quenching effect. The devices that use single‐layered neat films of [Ir(ppy)₂sb]PF₆ and [Ir(dFppy)₂sb]PF₆ achieve high peak external quantum efficiencies and power efficiencies of 7.1 % and 22.6 lm W^–1) at 2.5 V, and 7.1 % and 26.2 lm W^–1 at 2.8 V, respectively. These efficiencies are among the highest reported for solid‐state light‐emitting electrochemical cells, and indicate that cationic transition‐metal complexes containing ligands with good steric hindrance are excellent candidates for highly efficient solid‐state electrochemical cells.     

阻燃聚氨酯软质泡沫塑料中氯含量的测定

叙述了阻燃聚氨酯软质泡沫塑料中氯含量的测定方法:在助燃剂存在下,氧瓶燃烧使聚氨酯软质泡沫塑料中的有机氯转化为HCl,用稀NaOH吸收,使用硫氰酸汞分光光度法测定聚氨酯软质泡沫塑料中阻燃剂的氯含量。该方法简单快捷、精确度高,回收率为99.64%～102.41%。     

Fuzzy Learning of Talbot Effect Guides Optimal Mask Design for Proximity Field Nanopatterning Lithography

Processing methods used in photonics and nanotechnology possess many limitations restricting their application areas such as high cost, inability to produce fine details, problems with scalability, and long processing time. Proximity field nanopatterning is a lithography method which surpasses these limitations. By using interference patterns produced by a two-dimensional phase mask, the technique is able to generate a submicron detailed exposure on a millimeter-size slab of light sensitive photopolymer, which is then developed like a photographic plate to reveal three-dimensional interference patterns from the phase mask. While it is possible to use simulations to obtain the interference patterns produced by a phase mask, realizing the mask dimensions necessary for producing a desired interference pattern is analytically challenging due to the intricacies of light interactions involved in producing the final interference pattern. An alternative method is to iteratively optimize the phase mask until the interference patterns obtained converge to the desired pattern. However, depending on the optimization technique used, one either risks a significant probability of failure or requires a prohibitive number of iterations. We argue that an optimization technique that is to take advantage of the physics of the problem using machine learning methods (here fuzzy learning) can lead to competent mask design. This technique is described in this letter.     

Original Finger Image Extraction by Morphological Technique and Finger Image Comparisons for Persons' Identification

This research uses the object extracting technique to extract the index, middle and ring fingers from the hand images. The algorithm developed in this research can find the precise locations of the different fingers' fingertips and the finger-to-finger-valleys. After finding the positions of the fingertips and finger-valleys, the index, middle and ring fingers can be extracted from the hand images by using morphological technique. The extracted index, middle and ring fingers contain many useful geometry features. One can use these features to do the person's identification. The orientations of the index, middle and ring fingers are found in this research. Image rotating, image shifting, and image interpolating techniques are used to align different persons' index, middle and ring fingers. Image subtraction is used to exam the difference of two index, middle and ring finger images. In this research so far only use the index, middle and the ring fingers as the features to identify different persons. ^★This work was supported by National Science Council under grant NSC 93-2213-E-212-011.     

公斤工作基准稳定性误差的统计与分析

本文对力学室一等质量实验室的26、27、32三个公斤工作基准砝码的稳定性误差分别作了分析。经过对历年的检定记录和中间核查的分析汇总，得出各个公斤工作基准的稳定性误差，采用多个砝码多次全组合测量，利用最小二乘法计算出这三个公斤工作基准砝码之间的质量差值，找出它们的稳定性误差的变化趋势。     

Effects of contact shape on biological wet adhesion

Wet adhesion is widely adopted in biological adhesion systems in nature. Wet adhesion is studied in this paper with the focus on the effect of different contact shapes (flat, concave, convex, and ring-like) on the adhesion force. The evolution of the liquid bridge between a fiber tip and substrate during the detaching process shows two transition points. The first transition from the radius-controlled to the contact-angle controlled process is critical to influence the strength and robustness of adhesion. We show that a concave shape is more effective than a flat one, while a convex shape has no advantage. A ring-like contact shape has advantages in a hydrophobic environment and on a rough surface.     

分频解释技术在川西砂岩储层预测中的应用

分频解释技术是沿着储层或固定时窗对地震反射波各频率成分对应的调谐能量进行识别和成像,它避免了常规属性分析方法中的调谐陷阱,提高了识别薄储层的能力,能更客观地刻画地质体.在川西地区陆相隐蔽岩性气藏勘探中,存在调谐陷阱、波阻抗特征不明显、复杂地层结构中的有效薄储层不易识别等问题.为此,利用分频解释技术对川西地区侏罗系千佛崖组冲积扇相砾岩储层、上三叠统须四段河流三角洲相砂岩储层进行了描述.在多频率振幅叠加图上,冲积扇、三角洲水下分流河道等地质体形态和边界反映清晰;在单频振幅图上,清楚地显示出冲积扇内的辫状河道相薄层砾岩储层,与钻井结果相吻合,提高了储层预测精度.     

面向企业信息化实现管理现代化

为适应社会信息化技术的发展，必须积极推行企业信息化，企业信息化引发管理革命，从而丰富了企业管理现代化的内容。本文论述了上述三方面的内部及演化关系，指出只有面向企业信息化，才能充分实现企业管理现代化。     

催化重整装置的扩能改造

介绍湛江东兴炼油厂的重整装置由200kt／a扩能至300kt／a中有关催化重整反应动力学模拟计算软件的应用、反应工艺技术的改造、装置标定的情况。结合装置实际情况，采用两段装填、两段混氢技术提升了装置的技术水平。标定结果表明，改造后的装置达到了预期目的。